03786nam a22005895i 4500 978-981-99-8114-4 DE-He213 20251030110913.0 cr nn 008mamaa 240103s2024 si | s |||| 0|eng d 9789819981144 978-981-99-8114-4 10.1007/978-981-99-8114-4 doi TA401-492 QD505 TGM bicssc TEC021000 bisacsh TGMM thema Solar Light-to-Hydrogenated Organic Conversion [electronic resource] : Heterogeneous Photocatalysts / edited by Hairus Abdullah. 1st ed. 2024. Singapore : Springer Nature Singapore : Imprint: Springer, 2024. XI, 292 p. 194 illus., 145 illus. in color. online resource. text txt rdacontent computer c rdamedia online resource cr rdacarrier text file PDF rda Chapter 1 Photocatalytic reduction of nitrophenol and nitrobenzene with Zn oxysulfide semiconductor without using reducing agents -- Chapter 2 Photoreactions on hydrogen production and cleavage of azo bond in azobenzene over metal oxide and sulfide nanocatalysts in a mild condition -- Chapter 3 Photocatalytic oxygen reduction reaction to generate H2O2 over carbon-based nanosheet catalysts -- Chapter 4 Photocatalytic glycerol valorization into valuable chemicals and hydrogen generation on nanocatalysts -- Chapter 5 Photocatalysis on selective hydroxylation of benzene to phenol. This book highlights the promising photocatalytic methods for synthesizing organic chemicals by simultaneously degrading the toxicity of raw substances used for organic synthesis. It presents various semiconducting materials with high catalytic activities in hydrogen evolution reactions (HERs) and hydrogenation reactions, as well as the material characterizations for identifying semiconductor photocatalysts. The focus is on understanding the hydrogen dissociation and activation of substances in the process of hydrogenation and the fabrication of nanostructured catalysts with desired activity and selectivity. Recent works show photocatalytic hydrogenation reactions with in situ generated H+ on catalyst surfaces utilizing initial chemicals such as nitrophenol, nitrobenzene, azobenzene, and benzene for valorization. In addition, the photocatalytic valorization of waste glycerol is also discussed. Besides the hydrogenation reactions, the reduction of oxygen to form H2O2 can be done with aphotocatalytic method in atmospheric conditions. Some related perspectives and outlooks are also discussed for possible future development. Heterogeneous catalysis. 69155 Materials. Catalysis. 66843 Nanoscience. 65329 Photocatalysis. 67309 Heterogeneneous Catalysis. 69156 Catalysis. 66843 Nanophysics. 67377 Photocatalysis. 67309 Metal-organic Frameworks. 69157 Abdullah, Hairus. editor. edt http://id.loc.gov/vocabulary/relators/edt 67382 SpringerLink (Online service) Springer Nature eBook Printed edition: 9789819981137 Printed edition: 9789819981151 Printed edition: 9789819981168 https://doi.org/10.1007/978-981-99-8114-4 ZDB-2-CMS ZDB-2-SXC 57072 57072