03531nam a22004455i 4500001001800000003000900018005001700027007001500044008004100059020003700100024003500137050001400172072001600186072002300202072001500225245010100240250001800341264006900359300003500428336002600463337002600489338003600515347002400551490005700575505091100632520106901543650003102612650003002643700008902673710003402762773002602796776003602822776003602858776003602894830006402930856004602994912001403040912001403054999001703068978-3-031-48952-5DE-He21320251030110916.0cr nn 008mamaa240106s2024    sz |    s    |||| 0|eng d  a97830314895259978-3-031-48952-57 a10.1007/978-3-031-48952-52doi 4aQD241-441 7aPNN2bicssc 7aSCI0130402bisacsh 7aPNN2thema10aDehydrogenation Reactions with 3d Metalsh[electronic resource] /cedited by Basker Sundararaju.  a1st ed. 2024. 1aCham :bSpringer Nature Switzerland :bImprint: Springer,c2024.  aVIII, 305 p.bonline resource.  atextbtxt2rdacontent  acomputerbc2rdamedia  aonline resourcebcr2rdacarrier  atext filebPDF2rda1 aTopics in Organometallic Chemistry,x1616-8534 ;v730 aDehydrogenation of Alcohols Using 4 Transition Metal Catalysts: History 5 and Applications -- 3d-Metal catalyzed C-C bond formation through -alkylation of ketones -- 3d-Metal Catalyzed C-C Bond Formation Through α-Alkylation of Ester, Amide, and Nitriles With Alcohol via Dehydrogenative Coupling -- Current State-of-Art in the Guerbet-Type b-Alkylation of Secondary Alcohols with Primary Alcohols Catalyzed by Complexes Based on 3d-Metals -- Tandem multicomponent reactions for diverse heterocycles synthesis under 3d-transition metal catalysis -- Catalytic methylation using methanol as C1 source -- Recent Advancement of 3d Metal‐Catalyzed Ethanol Upgradation via the Guerbet Reaction -- Reformation of Alcohols to Esters, Acids, Amides, Ureas, Polyureas, and Polyethyleneimine by 3d-metal catalysts -- A Mechanistic Analysis of Dehydrogenation Reactions with First-row Transition Metal Complexes.  aIn this book recent developments in dehydrogenation reactions catalyzed by 3d-metals are discussed. With continue efforts to develop sustainable chemical production the discovery of new catalysts and catalytic procedures for (de)hydrogenation reactions are a subject of great interest to the chemistry community. Additionally, (de)hydrogenation reactions enable the creation of closed-loop production cycles that support a circular economy. The chapters presented include the synthesis of heterocycles and tandem-multicomponent (three or more) reactions through dehydrogenative strategy, as well as the conversion of ethanol to n-butanol, higher oxidized hydrocarbons like acids, ester, amides from alcohols, α-alkylation of amines, ketones, and amides with alcohols and mechanistic understanding of dehydrogenation reactions with high-valent metals. With contributions from experts in the field, the book is a valuable resource for scholars working in the field of organometallic chemistry, catalysis, medicinal chemistry, as well as researchers in the industry. 0aChemistry, Organic.96532514aOrganic Chemistry.9653271 aSundararaju, Basker.eeditor.4edt4http://id.loc.gov/vocabulary/relators/edt9693112 aSpringerLink (Online service)0 tSpringer Nature eBook08iPrinted edition:z978303148951808iPrinted edition:z978303148953208iPrinted edition:z9783031489549 0aTopics in Organometallic Chemistry,x1616-8534 ;v7396931240uhttps://doi.org/10.1007/978-3-031-48952-5  aZDB-2-CMS  aZDB-2-SXC  c57116d57116