04573nam a22005415i 4500001001800000003000900018005001700027007001500044008004100059020003700100024003500137050001200172072001700184072002300201072001600224100008200240245012700322250001800449264007200467300006800539336002600607337002600633338003600659347002400695505117500719520145701894650003003351650002103381650003003402650002503432650002203457650002503479650002103504650003003525650002503555650002203580700008203602700008803684710003403772773002603806776003603832776003603868776003603904856004603940912001403986912001404000999001704014978-981-97-0391-3DE-He21320251030111753.0cr nn 008mamaa240329s2024    si |    s    |||| 0|eng d  a97898197039139978-981-97-0391-37 a10.1007/978-981-97-0391-32doi 4aQD95-96 7aPNFS2bicssc 7aSCI0130502bisacsh 7aPNFS2thema1 aSato, Hisako.eauthor.4aut4http://id.loc.gov/vocabulary/relators/aut97433710aMulti-dimensional Vibrational Circular Dichroismh[electronic resource] /cby Hisako Sato, Jun Yoshida, Akihiko Yamagishi.  a1st ed. 2024. 1aSingapore :bSpringer Nature Singapore :bImprint: Springer,c2024.  aXIII, 209 p. 149 illus., 124 illus. in color.bonline resource.  atextbtxt2rdacontent  acomputerbc2rdamedia  aonline resourcebcr2rdacarrier  atext filebPDF2rda0 aPreface -- Chapter 1. Introduction -- Chapter 2. Basic features of vibrational circular dichroism (VCD) spectroscopy: A unique role for analyzing supramolecular chirality -- Chapter 3. Construction of the multi-dimensional VCD system -- Chapter 4. Molecular organization of gel fibrils as revealed by VCD -- Chapter 5. Dynamical VCD for sol-gel transformation -- Chapter 6. VCD enhancement on coordination: Mono-nuclear metal complexes -- Chapter 7. Chiral tectonics promoted by VCD: Multi-nuclear complexes -- Chapter 8. Solid-state VCD of inorganic intercalation compounds -- Chapter 9. VCD probing intermolecular interactions: Molecular crystals, acid-base pairs, host-guest association and solvation -- Chapter 10. VCD challenged to interfacial supramolecular chirality -- Chapter 11. VCD of inorganic supramolecular chirality -- Chapter 12. Use of circularly polarized infra-red light to liquid crystals -- Chapter 13. VCD of biological substances: Effects of D-amino acid residues on supramolecular chirality -- Chapter 14. Microscopic VCD scanning of biological organs -- Chapter 15. Future perspectives of VCD -- Bibliography: 17 year’s running on a tightrope.  aThis book provides the reader with the latest research on vibrational circular dichroism (VCD) spectroscopy including its useful features and applications to many fields. The book starts from an unresolved question in gel chemistry of how component molecules are organized in the flexible fibrils of gels. VCD spectroscopy was successful in giving a clear answer to this mystery. The book also describes a key aspect of this technique lay in the fact that VCD signals were remarkably enhanced when chiral molecules formed a stereoregular molecular array over a few hundred nanometers. VCD spectroscopy was also applied to other topics involving chiral molecules such as the chiral discrimination mechanism in heterogeneous asymmetric catalysis and the build-up of supramolecular chirality in molecular crystals. Furthermore, the book covers the recent instrument developments leading to multi-dimensional VCD measurements with the coordinates of wavenumber, space and time. This progress has opened up new biological and medical applications such as the heterogenous distributions of protein domains in insect wings and the quality control of chiral drugs. The last part of the book presents the possibility of medical diagnosis of Alzheimer’s disease through multi-dimensional VCD analyses. This book appeals not only to researchers and students who study spectroscopy but also to ones in catalysis, biology and medicine as users of the VCD methods. 0aSpectrum analysis.969373 0aPolymers.966724 0aSupramolecular chemistry. 0aMedicinal chemistry. 0aDiagnosis.96494214aSpectroscopy.96937524aPolymers.96672424aSupramolecular Chemistry.24aMedicinal Chemistry.24aDiagnosis.9649421 aYoshida, Jun.eauthor.4aut4http://id.loc.gov/vocabulary/relators/aut9743381 aYamagishi, Akihiko.eauthor.4aut4http://id.loc.gov/vocabulary/relators/aut9743392 aSpringerLink (Online service)0 tSpringer Nature eBook08iPrinted edition:z978981970390608iPrinted edition:z978981970392008iPrinted edition:z978981970393740uhttps://doi.org/10.1007/978-981-97-0391-3  aZDB-2-CMS  aZDB-2-SXC  c58788d58788