03609nam a22005055i 4500001001800000003000900018005001700027007001500044008004100059020003700100024003500137050001600172072001700188072002300205072001600228245012100244250001800365264007500383300003400458336002600492337002600518338003600544347002400580490005700604505053900661520123001200650003902430650002202469650003202491650003702523650002202560650003202582700008202614700008402696710003402780773002602814776003602840776003602876776003602912830006402948856004603012912001403058912001403072999001703086978-3-031-57381-1DE-He21320251030112240.0cr nn 008mamaa240529s2024    sz |    s    |||| 0|eng d  a97830315738119978-3-031-57381-17 a10.1007/978-3-031-57381-12doi 4aQD410-412.5 7aPNND2bicssc 7aSCI0130402bisacsh 7aPNND2thema10aMetallocenes in Regio- and Stereoselective Synthesish[electronic resource] /cedited by Marko Hapke, Martin Kotora.  a1st ed. 2024. 1aCham :bSpringer International Publishing :bImprint: Springer,c2024.  aVII, 204 p.bonline resource.  atextbtxt2rdacontent  acomputerbc2rdamedia  aonline resourcebcr2rdacarrier  atext filebPDF2rda1 aTopics in Organometallic Chemistry,x1616-8534 ;v740 aSynthesis and Application of Highly Substituted Cyclopentadienes -- Synthesis of 1,2-Disubstituted Cyclopentadienes and Their Application -- Synthesis and application of novel chiral Cp ligands in transition metal catalysis -- Selective synthesis of and with chiral ferrocenes -- Knölker-type catalysts for (asymmetric) hydrogenation reactions -- Selective transformations mediated by group 4 metal cyclopentadienyl complexes -- Naturally Occurring Cyclopentadienes and Cyclopentadienyl Anions -- Naturally Occurring Diazofluorenes.  aThis book presents the latest synthetic protocols for the assembly of functionalized Cp ligands and their transition metal complexes. Cyclopentadienyl (Cp) complexes of transition metals belong to the most important classes of transition metal complexes with s-bound ligands in the coordination sphere since their discovery in the middle of the last century. Even though known for a long time, this class of complexes constantly evolves to deliver novel modified Cp ligands and to blossom into new fields of application. As well as the synthesis of ligands and complexes this book concentrates on novel and prospering fields of application in organic synthesis. In this respect the Cp complexes have been applied to induce and catalyze various chemical transformations such as new C-C bond formation involving unsaturated substrates (e.g. cyclotrimerizations, cycloadditions, carbometallations, etc.), the C―H bond and C―C activations followed by subsequent reactions (e.g. arylation, alkenylations, annulations, etc.), as well as many other processes which are discussed. This volume also covers the recent application of chiral Cp complexes in enantioselective synthesis and as essential parts of many ligand systems. . 0aOrganometallic chemistry .977708 0aCatalysis.966843 0aInorganic chemistry.96528414aOrganometallic Chemistry.97770924aCatalysis.96684324aInorganic Chemistry.9652841 aHapke, Marko.eeditor.4edt4http://id.loc.gov/vocabulary/relators/edt9777101 aKotora, Martin.eeditor.4edt4http://id.loc.gov/vocabulary/relators/edt9777112 aSpringerLink (Online service)0 tSpringer Nature eBook08iPrinted edition:z978303157380408iPrinted edition:z978303157382808iPrinted edition:z9783031573835 0aTopics in Organometallic Chemistry,x1616-8534 ;v7496931240uhttps://doi.org/10.1007/978-3-031-57381-1  aZDB-2-CMS  aZDB-2-SXC  c60244d60244