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020 _a9789819981144
_9978-981-99-8114-4
024 7 _a10.1007/978-981-99-8114-4
_2doi
050 4 _aTA401-492
050 4 _aQD505
072 7 _aTGM
_2bicssc
072 7 _aTEC021000
_2bisacsh
072 7 _aTGMM
_2thema
245 1 0 _aSolar Light-to-Hydrogenated Organic Conversion
_h[electronic resource] :
_bHeterogeneous Photocatalysts /
_cedited by Hairus Abdullah.
250 _a1st ed. 2024.
264 1 _aSingapore :
_bSpringer Nature Singapore :
_bImprint: Springer,
_c2024.
300 _aXI, 292 p. 194 illus., 145 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
505 0 _aChapter 1 Photocatalytic reduction of nitrophenol and nitrobenzene with Zn oxysulfide semiconductor without using reducing agents -- Chapter 2 Photoreactions on hydrogen production and cleavage of azo bond in azobenzene over metal oxide and sulfide nanocatalysts in a mild condition -- Chapter 3 Photocatalytic oxygen reduction reaction to generate H2O2 over carbon-based nanosheet catalysts -- Chapter 4 Photocatalytic glycerol valorization into valuable chemicals and hydrogen generation on nanocatalysts -- Chapter 5 Photocatalysis on selective hydroxylation of benzene to phenol.
520 _aThis book highlights the promising photocatalytic methods for synthesizing organic chemicals by simultaneously degrading the toxicity of raw substances used for organic synthesis. It presents various semiconducting materials with high catalytic activities in hydrogen evolution reactions (HERs) and hydrogenation reactions, as well as the material characterizations for identifying semiconductor photocatalysts. The focus is on understanding the hydrogen dissociation and activation of substances in the process of hydrogenation and the fabrication of nanostructured catalysts with desired activity and selectivity. Recent works show photocatalytic hydrogenation reactions with in situ generated H+ on catalyst surfaces utilizing initial chemicals such as nitrophenol, nitrobenzene, azobenzene, and benzene for valorization. In addition, the photocatalytic valorization of waste glycerol is also discussed. Besides the hydrogenation reactions, the reduction of oxygen to form H2O2 can be done with aphotocatalytic method in atmospheric conditions. Some related perspectives and outlooks are also discussed for possible future development.
650 0 _aHeterogeneous catalysis.
_969155
650 0 _aMaterials.
650 0 _aCatalysis.
_966843
650 0 _aNanoscience.
_965329
650 0 _aPhotocatalysis.
_967309
650 1 4 _aHeterogeneneous Catalysis.
_969156
650 2 4 _aCatalysis.
_966843
650 2 4 _aNanophysics.
_967377
650 2 4 _aPhotocatalysis.
_967309
650 2 4 _aMetal-organic Frameworks.
_969157
700 1 _aAbdullah, Hairus.
_eeditor.
_4edt
_4http://id.loc.gov/vocabulary/relators/edt
_967382
710 2 _aSpringerLink (Online service)
773 0 _tSpringer Nature eBook
776 0 8 _iPrinted edition:
_z9789819981137
776 0 8 _iPrinted edition:
_z9789819981151
776 0 8 _iPrinted edition:
_z9789819981168
856 4 0 _uhttps://doi.org/10.1007/978-981-99-8114-4
912 _aZDB-2-CMS
912 _aZDB-2-SXC
999 _c57072
_d57072