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020 _a9783031573811
_9978-3-031-57381-1
024 7 _a10.1007/978-3-031-57381-1
_2doi
050 4 _aQD410-412.5
072 7 _aPNND
_2bicssc
072 7 _aSCI013040
_2bisacsh
072 7 _aPNND
_2thema
245 1 0 _aMetallocenes in Regio- and Stereoselective Synthesis
_h[electronic resource] /
_cedited by Marko Hapke, Martin Kotora.
250 _a1st ed. 2024.
264 1 _aCham :
_bSpringer International Publishing :
_bImprint: Springer,
_c2024.
300 _aVII, 204 p.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aTopics in Organometallic Chemistry,
_x1616-8534 ;
_v74
505 0 _aSynthesis and Application of Highly Substituted Cyclopentadienes -- Synthesis of 1,2-Disubstituted Cyclopentadienes and Their Application -- Synthesis and application of novel chiral Cp ligands in transition metal catalysis -- Selective synthesis of and with chiral ferrocenes -- Knölker-type catalysts for (asymmetric) hydrogenation reactions -- Selective transformations mediated by group 4 metal cyclopentadienyl complexes -- Naturally Occurring Cyclopentadienes and Cyclopentadienyl Anions -- Naturally Occurring Diazofluorenes.
520 _aThis book presents the latest synthetic protocols for the assembly of functionalized Cp ligands and their transition metal complexes. Cyclopentadienyl (Cp) complexes of transition metals belong to the most important classes of transition metal complexes with s-bound ligands in the coordination sphere since their discovery in the middle of the last century. Even though known for a long time, this class of complexes constantly evolves to deliver novel modified Cp ligands and to blossom into new fields of application. As well as the synthesis of ligands and complexes this book concentrates on novel and prospering fields of application in organic synthesis. In this respect the Cp complexes have been applied to induce and catalyze various chemical transformations such as new C-C bond formation involving unsaturated substrates (e.g. cyclotrimerizations, cycloadditions, carbometallations, etc.), the C―H bond and C―C activations followed by subsequent reactions (e.g. arylation, alkenylations, annulations, etc.), as well as many other processes which are discussed. This volume also covers the recent application of chiral Cp complexes in enantioselective synthesis and as essential parts of many ligand systems. .
650 0 _aOrganometallic chemistry .
_977708
650 0 _aCatalysis.
_966843
650 0 _aInorganic chemistry.
_965284
650 1 4 _aOrganometallic Chemistry.
_977709
650 2 4 _aCatalysis.
_966843
650 2 4 _aInorganic Chemistry.
_965284
700 1 _aHapke, Marko.
_eeditor.
_4edt
_4http://id.loc.gov/vocabulary/relators/edt
_977710
700 1 _aKotora, Martin.
_eeditor.
_4edt
_4http://id.loc.gov/vocabulary/relators/edt
_977711
710 2 _aSpringerLink (Online service)
773 0 _tSpringer Nature eBook
776 0 8 _iPrinted edition:
_z9783031573804
776 0 8 _iPrinted edition:
_z9783031573828
776 0 8 _iPrinted edition:
_z9783031573835
830 0 _aTopics in Organometallic Chemistry,
_x1616-8534 ;
_v74
_969312
856 4 0 _uhttps://doi.org/10.1007/978-3-031-57381-1
912 _aZDB-2-CMS
912 _aZDB-2-SXC
999 _c60244
_d60244