| 000 | 03699nam a22005655i 4500 | ||
|---|---|---|---|
| 001 | 978-3-031-68646-7 | ||
| 003 | DE-He213 | ||
| 005 | 20251030114920.0 | ||
| 007 | cr nn 008mamaa | ||
| 008 | 250104s2024 sz | s |||| 0|eng d | ||
| 020 |
_a9783031686467 _9978-3-031-68646-7 |
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| 024 | 7 |
_a10.1007/978-3-031-68646-7 _2doi |
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| 050 | 4 | _aQC170-197 | |
| 072 | 7 |
_aPHM _2bicssc |
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| 072 | 7 |
_aSCI074000 _2bisacsh |
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| 072 | 7 |
_aPHM _2thema |
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| 100 | 1 |
_aBřezina, Václav. _eauthor. _4aut _4http://id.loc.gov/vocabulary/relators/aut _990142 |
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| 245 | 1 | 0 |
_aSupramolecular Complexes of Oxoporphyrinogens with Organic Molecules _h[electronic resource] / _cby Václav Březina. |
| 250 | _a1st ed. 2024. | ||
| 264 | 1 |
_aCham : _bSpringer Nature Switzerland : _bImprint: Springer, _c2024. |
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| 300 |
_aXV, 214 p. 126 illus., 102 illus. in color. _bonline resource. |
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| 336 |
_atext _btxt _2rdacontent |
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| 337 |
_acomputer _bc _2rdamedia |
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| 338 |
_aonline resource _bcr _2rdacarrier |
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| 347 |
_atext file _bPDF _2rda |
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| 490 | 1 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5061 |
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| 505 | 0 | _aIntroduction -- Quantitative description ofsupramolecular binding -- Nuclear magnetic resonancespectroscopy -- UV/vis spectroscopy -- Singular value decomposition -- Chromic and binding propertiesof OxP derivatives -- Dynamic processes and chemicalexchange in OxP derivatives -- Conclusion. | |
| 520 | _aMacrocyclic oxoporphyrinogen molecules combine the ability to form strong supramolecular complexes with organic compounds and the ability to absorb light. These properties allow high-sensitivity colorimetric detection of acids in solution in the presence of oxoporphyrinogen. Moreover, protonated oxoporphyrinogens show various molecular dynamic processes on the millisecond timescale. This book offers deep analyses of colorimetric, binding and kinetic properties of oxoporphyrinogen-acid complexes. A detailed introduction is given for: theory of supramolecular binding and chemical kinetics; NMR spectroscopy with emphasis on multi-state chemical exchange including derivation of analytical spectral lineshapes; UV/vis spectroscopy and analysis of UV/vis spectra, using singular value decomposition (SVD). Implementation of the derived models in Mathematica is also provided. The experimental part addresses SVD analysis of UV/vis spectra illuminating the effect of protonation on various oxoporphyrinogen derivatives and explaining the colorimetric response. Furthermore, analysis of chemical exchange lineshapes offers insight into the dynamic processes present in protonated oxoporphyrinogens. The various models and techniques described in this book are widely applicable for other systems. | ||
| 650 | 0 |
_aAtoms. _968249 |
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| 650 | 0 |
_aMolecules. _968617 |
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| 650 | 0 |
_aNuclear magnetic resonance. _982883 |
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| 650 | 0 |
_aChemical detectors. _965822 |
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| 650 | 1 | 4 |
_aAtomic, Molecular and Chemical Physics. _974570 |
| 650 | 2 | 4 |
_aBio- and Macromolecules. _975488 |
| 650 | 2 | 4 |
_aMagnetic Resonance (NMR, EPR). _982884 |
| 650 | 2 | 4 |
_aSensors. _965825 |
| 710 | 2 | _aSpringerLink (Online service) | |
| 773 | 0 | _tSpringer Nature eBook | |
| 776 | 0 | 8 |
_iPrinted edition: _z9783031686450 |
| 776 | 0 | 8 |
_iPrinted edition: _z9783031686474 |
| 776 | 0 | 8 |
_iPrinted edition: _z9783031686481 |
| 830 | 0 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5061 _966370 |
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| 856 | 4 | 0 | _uhttps://doi.org/10.1007/978-3-031-68646-7 |
| 912 | _aZDB-2-PHA | ||
| 912 | _aZDB-2-SXP | ||
| 999 |
_c66334 _d66334 |
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