000			03423nam a22003734u 4500
001			10.1002/9783527830879
003			Wiley
005			20251030120314.0
007			cr nn 008mam|a
008			240126t2024||||xxu fs| |0|| 0|eng||
020			_a9783527830879 _qelectronic
024	7		_a10.1002/9783527830879 _2doi
041			_aeng
245	0	0	_aRedox‐Active Ligands _bConcepts and Catalysis _h[electronic resource] _cEdited by Marine Desage‐El Murr.
250			_a1
260			_bWiley _c2024
264		1	_bWiley _c2024
300			_a368pp.;
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _2rdaft
347			_bPDF
520			_aAuthoritative resource showcasing a new family of ligands that can lead to better catalysts and promising applications in organic synthesis Redox-Active Ligands gives a comprehensive overview of the unique features of redox-active ligands, describing their structure and synthesis, the characterization of their coordination complexes, and important applications in homogeneous catalysis. The work reflects the diversity of the subject by including ongoing research spanning coordination chemistry, organometallic chemistry, bioinspired catalysis, proton and electron transfer, and the ability of such ligands to interact with early and late transition metals, lanthanides, and actinides. The book is divided into three parts, devoted to introduction and concepts, applications, and case studies. After the introduction on key concepts related to the field, and the different types of ligands and complexes in which ligand-centered redox activity is commonly observed, mechanistic and computational studies are described. The second part focuses on catalytic applications of redox-active complexes, including examples from radical transformations, coordination chemistry and organic synthesis. Finally, case studies of redox-active guanidine ligands, and of lanthanides and actinides are presented. Other specific sample topics covered include: An overview of the electronic features of redox-active ligands, covering their historical perspective and biological background The versatility and mode of action of redox-active ligands, which sets them apart from more classic and tunable ligands such as phosphines or N-heterocyclic carbenes Preparation and catalytic applications of complexes of stable N-aryl radicals Metal complexes with redox-active ligands in H+/e-transfer transformations By providing up-to-date information on important concepts and applications, Redox-Active Ligands is an essential reading for researchers working in organometallic and coordination chemistry, catalysis, organic synthesis, and (bio)inorganic chemistry, as well as newcomers to the field.
650		4	_aOrganometallic Chemistry
650		4	_aCatalysis _966843
650		4	_aCoordination Chemistry _970558
700	1		_aDesage‐El Murr, Marine _4edt _991908
776	0	8	_iPrinted edition: _z9783527348503
856	4	0	_uhttps://doi.org/10.1002/9783527830879 _aWiley Online Library
856	4	0	_uhttps://onlinelibrary.wiley.com/action/showBook?doi=10.1002%2F9783527830879 _aWiley Online Library
856	4	2	_3Cover Image _uhttps://onlinelibrary.wiley.com/cms/asset/f5d08b6a-e41e-48c0-ae88-2aca9955f745/9783527830879.cover.gif _aWiley Online Library
999			_c67140 _d67140